二次旋转设计和反向人工神经网络在铅、镉、汞、镍同时测定中的应用

利用二次通用旋转组合设计法建立了吸光度与显色剂，增敏剂用量及pH 值之间的数学模型，进而得出使吸光度最大的显色剂用量，增敏剂用量及PH值，在优化的基础上，用B－P人工地Pb,Cd,Hg,Ni同时测定的数据进行解析，并与经典最小二乘法进行了对比，结果较准确。     

基于粗集理论的组合预测法在无形资产评估中的应用

针对如何评估企业无形资产的问题,运用基于粗集理论的组合预测方法,建立了企业无形资产评估的数量模型。该模型的特点是将组合预测方法中权系数的确定问题转化为粗集理论中的属性重要性评价问题,这样就在很大程度上克服了传统组合预测方法中权系数确定主观性太大的缺陷,而使得权系数的确定更具客观性。最后,结合实例阐述了基于粗集理论的组合预测方法在企业无形资产评估中的应用,进一步说明了该方法的可行性和有效性。     

研究岩石破裂等弱化行为的力－位移组合控制方法

本文介绍了一种用力和位移的线性组合控制岩石试验的新方法。该方法已在一台自制的伺服实验系统上和一台MTS实验系统上得到了实现。用这种方法能够简便地求出通常难以求出的具有Ⅱ类特性岩石的全应力-应变曲线,而且能够变化出如广义应力松驰等其它实验类型,从而能够对时间依赖性进行深入的研究。由于其易于采用的特点,它在研究岩石破裂乃至摩擦等弱化过程方面有着广泛的应用前景。     

Application of in-plasma catalysis and post-plasma catalysis for methane partial oxidation to methanol over a Fe2O3-CuO/γ-Al2O3 catalyst

Methane partial oxidation to methanol (MPOM) using dielectric barrier discharge over a Fe2O3-CuO/γ-Al2O3 catalyst was performed. The multicomponent catalyst was combined with plasma in two different configurations, i.e., in-plasma catalysis (IPC) and post-plasma catalysis (PPC). It was found that the catalytic performance of the catalysts for MPOM was strongly dependent on the hybrid configuration. A better synergistic performance of plasma and catalysis was achieved in the IPC configuration, but the catalysts packed in the discharge zone showed lower stability than those connected to the discharge zone in sequence. Active species, such as ozone, atomic oxygen and methyl radicals, were produced from the plasma-catalysis process, and made a major contribution to methanol synthesis. These active species were identified by the means of in situ optical emission spectra, ozone measurement and FT-IR spectra. It was confirmed that the amount of active species in the IPC system was greater than that in the PPC system. The results of TG, XRD, and N2 adsorption-desorption revealed that carbon deposition on the spent catalyst surface was responsible for the catalyst deactivation in the IPC configuration.     

Convex hull: A new method to determine the separation space used and to optimize operating conditions for comprehensive two-dimensional gas chromatography

It is important to develop methods of optimizing the selection of column sets and operating conditions for comprehensive two-dimensional gas chromatography. A new method for the calculation of the percentage of separation space used was developed using Delaunay's triangulation algorithms (convex hull). This approach was compared with an existing method and showed better precision and accuracy. It was successfully applied to the selection of the most convenient column set and the geometrical parameters of second column for the analysis of 49 target compounds in wastewater.     

Wave optics simulation approach for high-power laser beam combination

A numerical wave optics approach for simulating multiplex super Gaussian beam combination in high-power laser facility is presented. The approach involves the application of a sequence of random phase screens and von Karman turbulence phase to an initial beam field and the summation of the intensity results. The analytical and numerical calculation results have been given to illustrate the properties of the resulting far-field pattern after coherent, incoherent and spatially coherent combination, and some of that are compared with experimental results. The approach can be used for modeling and evaluating applications such as high-power laser shooting that might utilize different beams combining approach.     

量子棒中强耦合杂质束缚极化子的振动频率

给出了具有椭球边界量子棒经坐标变换成球形边界的哈密顿量。采用线性组合算符和幺正变换的方法研究了在非均匀抛物限制势下量子棒中强耦合杂质束缚极化子的性质。导出了量子棒中强耦合杂质束缚极化子的振动频率和声子平均数随库仑束缚势、电子-声子耦合强度、椭球的纵横比和量子棒的横向和纵向有效受限长度的变化关系。数值计算结果表明:振动频率和声子平均数随电子-声子耦合强度和库仑束缚势的增强而增加,随量子棒的横向和纵向有效受限长度和椭球的纵横比的减小而增大。表现出量子棒的奇特的量子尺寸限制效应。     

激光相干合成中单元的相位和振幅波动对合成光束远场分布的影响

运用傅里叶光学分析法推导出系统抖动造成单个光源的相位和振幅发生波动时的远场光强表达式,以1维阵列为例分析了系统抖动对远场的影响.研究表明:随着参与合束的发光单元数目的增加,尖峰变锐,能量更集中;系统抖动引起了远场峰值光强的减少.出现了本底现象,破坏了远场的对称性和光束质量;激光阵列单个光源的相位随机抖动应该控制在3 π/8范围内;相干合束发光单元数目越多,系统抖动对远场的影响越小.     

平顶高斯超短脉冲激光的时间部分相干性对相干合成的影响

 利用准单色光干涉理论,计算了2×2平顶高斯超短脉冲激光在远场的干涉图样,分析了激光的时间部分相干性及其存在束间相位差时对相干合成的影响。计算结果表明,当单路激光输出光束线宽小于100 nm时,理想波前的远场光斑图样和峰值光强基本保持不变,当光束线宽大于100 nm时,干涉减弱衍射效应逐渐增强;光束间存在相位差时,时间部分相干性将破坏远场图样随束间相位差的周期性变化,相位差越大干涉越弱;当超过相干长度时,则为非相干合成,但1/6倍相干长度范围内,仍可视为较理想的相干合成,此时焦斑的斯特列尔比大于0.9,对超短脉冲的相干合成影响可忽略。     

高平均功率固体激光功率和光束质量关系研究进展

 固体激光的一个重大发展方向和目标是实现“三高”(高平均功率、高光束质量和高效率)激光同时输出,结合相关研究工作和进展,着重论述了固体激光输出功率和光束质量的关系,给出了功率升高、光束质量非线性下降是当前“三高”固体激光研究的一个基本科学技术问题。围绕这一基本问题,评述了一些重要技术途径和手段,并探讨了实现高平均功率高光束质量固体激光输出的可能有效途径。